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An air-stable Dy(iii) single-ion magnet with high anisotropy barrier and blocking temperature

Herein we report air-stable Dy(iii) and Er(iii) single-ion magnets (SIMs) with pseudo-D(5h) symmetry, synthesized from a sterically encumbered phosphonamide, (t)BuPO(NH(i)Pr)(2), where the Dy(iii)-SIM exhibits a magnetization blocking (T(B)) up to 12 K, defined from the maxima of the zero-field cool...

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Detalles Bibliográficos
Autores principales: Gupta, Sandeep K., Rajeshkumar, Thayalan, Rajaraman, Gopalan, Murugavel, Ramaswamy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6020529/
https://www.ncbi.nlm.nih.gov/pubmed/30155168
http://dx.doi.org/10.1039/c6sc00279j