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Iridium-catalyzed selective 1,2-hydrosilylation of N-heterocycles
A silylene-bridged Ir dimer in situ generated from [Ir(coe)(2)Cl](2) and Et(2)SiH(2) was found to catalyze the hydrosilylation of N-heteroaromatics to furnish dearomatized azacyclic products with high activity (up to 1000 TONs), excellent selectivity, and good functional group tolerance. The substra...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6020754/ https://www.ncbi.nlm.nih.gov/pubmed/30155189 http://dx.doi.org/10.1039/c6sc01037g |