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Iridium-catalyzed selective 1,2-hydrosilylation of N-heterocycles

A silylene-bridged Ir dimer in situ generated from [Ir(coe)(2)Cl](2) and Et(2)SiH(2) was found to catalyze the hydrosilylation of N-heteroaromatics to furnish dearomatized azacyclic products with high activity (up to 1000 TONs), excellent selectivity, and good functional group tolerance. The substra...

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Detalles Bibliográficos
Autores principales:	Jeong, Jinseong, Park, Sehoon, Chang, Sukbok
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2016
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6020754/ https://www.ncbi.nlm.nih.gov/pubmed/30155189 http://dx.doi.org/10.1039/c6sc01037g

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