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Eradicating mass spectrometric glycan rearrangement by utilizing free radicals

Mass spectrometric glycan rearrangement is problematic because it provides misleading structural information. Here we report on a new reagent, a methylated free radical activated glycan sequencing reagent (Me-FRAGS), which combines a free radical precursor with a methylated pyridine moiety that can...

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Detalles Bibliográficos
Autores principales: Desai, Nikunj, Thomas, Daniel A., Lee, Jungeun, Gao, Jinshan, Beauchamp, J. L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6020757/
https://www.ncbi.nlm.nih.gov/pubmed/30155192
http://dx.doi.org/10.1039/c6sc01371f