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Guest and solvent modulated photo-driven charge separation and triplet generation in a perylene bisimide cyclophane
Cofacial positioning of two perylene bisimide (PBI) chromophores at a distance of 6.5 Å in a cyclophane structure prohibits the otherwise common excimer formation and directs photoexcited singlet state relaxation towards intramolecular symmetry-breaking charge separation (τ(CS) = 161 ± 4 ps) in pola...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6021749/ https://www.ncbi.nlm.nih.gov/pubmed/30034681 http://dx.doi.org/10.1039/c6sc01574c |