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Nickel-catalyzed cyclization of alkyne-nitriles with organoboronic acids involving anti-carbometalation of alkynes

A nickel-catalyzed regioselective addition/cyclization of o-(cyano)phenyl propargyl ethers with arylboronic acids has been developed, which provides an efficient protocol for the synthesis of highly functionalized 1-naphthylamines with wide structural diversity. The reaction is characterized by a re...

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Detalles Bibliográficos
Autores principales: Zhang, Xingjie, Xie, Xin, Liu, Yuanhong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6021782/
https://www.ncbi.nlm.nih.gov/pubmed/30034720
http://dx.doi.org/10.1039/c6sc01191h