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Enantioselective synthesis of Iboga alkaloids and vinblastine via rearrangements of quaternary ammoniums
An efficient and novel strategy for the enantioselective syntheses of various iboga alkaloids has been developed. The salient features include a gold-catalyzed oxidation of a terminal alkyne followed by cyclization, a Stevens rearrangement and a tandem sequence that combines the gold-catalyzed oxida...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6021789/ https://www.ncbi.nlm.nih.gov/pubmed/30034694 http://dx.doi.org/10.1039/c6sc00932h |