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Enantioselective synthesis of Iboga alkaloids and vinblastine via rearrangements of quaternary ammoniums

An efficient and novel strategy for the enantioselective syntheses of various iboga alkaloids has been developed. The salient features include a gold-catalyzed oxidation of a terminal alkyne followed by cyclization, a Stevens rearrangement and a tandem sequence that combines the gold-catalyzed oxida...

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Detalles Bibliográficos
Autores principales: Zhang, Yun, Xue, Yibin, Li, Gang, Yuan, Haosen, Luo, Tuoping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6021789/
https://www.ncbi.nlm.nih.gov/pubmed/30034694
http://dx.doi.org/10.1039/c6sc00932h