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[3-N(2)-o-C(2)B(10)H(11)][BF(4)]: a useful synthon for multiple cage boron functionalizations of o-carborane
A simple and efficient method for selective cage B(3) multiple functionalization of o-carborane is described. Reaction of [3-N(2)-o-C(2)B(10)H(11)][BF(4)] with various kinds of nucleophiles gave a very broad spectrum of cage B(3)-substituted o-carborane derivatives, 3-X-o-C(2)B(10)H(11) (X = OH, SCN...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6022115/ https://www.ncbi.nlm.nih.gov/pubmed/30034700 http://dx.doi.org/10.1039/c6sc01566b |