[3-N(2)-o-C(2)B(10)H(11)][BF(4)]: a useful synthon for multiple cage boron functionalizations of o-carborane

A simple and efficient method for selective cage B(3) multiple functionalization of o-carborane is described. Reaction of [3-N(2)-o-C(2)B(10)H(11)][BF(4)] with various kinds of nucleophiles gave a very broad spectrum of cage B(3)-substituted o-carborane derivatives, 3-X-o-C(2)B(10)H(11) (X = OH, SCN...

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Detalles Bibliográficos
Autores principales: Zhao, Da, Xie, Zuowei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6022115/
https://www.ncbi.nlm.nih.gov/pubmed/30034700
http://dx.doi.org/10.1039/c6sc01566b
Descripción
Sumario:A simple and efficient method for selective cage B(3) multiple functionalization of o-carborane is described. Reaction of [3-N(2)-o-C(2)B(10)H(11)][BF(4)] with various kinds of nucleophiles gave a very broad spectrum of cage B(3)-substituted o-carborane derivatives, 3-X-o-C(2)B(10)H(11) (X = OH, SCN, NH(2), NO(2), N(3), CF(3), PO(C(6)H(5))(2), etc). This reaction may serve as another efficient [(18)F]-radiolabeling method of carborane clusters for positron emission tomography applications.

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