[3-N(2)-o-C(2)B(10)H(11)][BF(4)]: a useful synthon for multiple cage boron functionalizations of o-carborane

A simple and efficient method for selective cage B(3) multiple functionalization of o-carborane is described. Reaction of [3-N(2)-o-C(2)B(10)H(11)][BF(4)] with various kinds of nucleophiles gave a very broad spectrum of cage B(3)-substituted o-carborane derivatives, 3-X-o-C(2)B(10)H(11) (X = OH, SCN...

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Detalles Bibliográficos
Autores principales: Zhao, Da, Xie, Zuowei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6022115/
https://www.ncbi.nlm.nih.gov/pubmed/30034700
http://dx.doi.org/10.1039/c6sc01566b
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author Zhao, Da
Xie, Zuowei
author_facet Zhao, Da
Xie, Zuowei
author_sort Zhao, Da
collection PubMed
description A simple and efficient method for selective cage B(3) multiple functionalization of o-carborane is described. Reaction of [3-N(2)-o-C(2)B(10)H(11)][BF(4)] with various kinds of nucleophiles gave a very broad spectrum of cage B(3)-substituted o-carborane derivatives, 3-X-o-C(2)B(10)H(11) (X = OH, SCN, NH(2), NO(2), N(3), CF(3), PO(C(6)H(5))(2), etc). This reaction may serve as another efficient [(18)F]-radiolabeling method of carborane clusters for positron emission tomography applications.
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spelling pubmed-60221152018-07-20 [3-N(2)-o-C(2)B(10)H(11)][BF(4)]: a useful synthon for multiple cage boron functionalizations of o-carborane Zhao, Da Xie, Zuowei Chem Sci Chemistry A simple and efficient method for selective cage B(3) multiple functionalization of o-carborane is described. Reaction of [3-N(2)-o-C(2)B(10)H(11)][BF(4)] with various kinds of nucleophiles gave a very broad spectrum of cage B(3)-substituted o-carborane derivatives, 3-X-o-C(2)B(10)H(11) (X = OH, SCN, NH(2), NO(2), N(3), CF(3), PO(C(6)H(5))(2), etc). This reaction may serve as another efficient [(18)F]-radiolabeling method of carborane clusters for positron emission tomography applications. Royal Society of Chemistry 2016-09-01 2016-06-08 /pmc/articles/PMC6022115/ /pubmed/30034700 http://dx.doi.org/10.1039/c6sc01566b Text en This journal is © The Royal Society of Chemistry 2016 https://creativecommons.org/licenses/by/3.0/This article is freely available. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0)
spellingShingle Chemistry
Zhao, Da
Xie, Zuowei
[3-N(2)-o-C(2)B(10)H(11)][BF(4)]: a useful synthon for multiple cage boron functionalizations of o-carborane
title [3-N(2)-o-C(2)B(10)H(11)][BF(4)]: a useful synthon for multiple cage boron functionalizations of o-carborane
title_full [3-N(2)-o-C(2)B(10)H(11)][BF(4)]: a useful synthon for multiple cage boron functionalizations of o-carborane
title_fullStr [3-N(2)-o-C(2)B(10)H(11)][BF(4)]: a useful synthon for multiple cage boron functionalizations of o-carborane
title_full_unstemmed [3-N(2)-o-C(2)B(10)H(11)][BF(4)]: a useful synthon for multiple cage boron functionalizations of o-carborane
title_short [3-N(2)-o-C(2)B(10)H(11)][BF(4)]: a useful synthon for multiple cage boron functionalizations of o-carborane
title_sort [3-n(2)-o-c(2)b(10)h(11)][bf(4)]: a useful synthon for multiple cage boron functionalizations of o-carborane
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6022115/
https://www.ncbi.nlm.nih.gov/pubmed/30034700
http://dx.doi.org/10.1039/c6sc01566b
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