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Embedding electron-deficient nitrogen atoms in polymer backbone towards high performance n-type polymer field-effect transistors

With sp(2)-nitrogen atoms embedded in an isatin unit, a donor–acceptor (D–A) conjugated polymer AzaBDOPV-2T was developed with a low LUMO level down to –4.37 eV. The lowered LUMO level as well as the conformation-locked planar backbone provide AzaBDOPV-2T with electron mobilities over 3.22 cm(2) V(–...

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Detalles Bibliográficos
Autores principales: Dai, Ya-Zhong, Ai, Na, Lu, Yang, Zheng, Yu-Qing, Dou, Jin-Hu, Shi, Ke, Lei, Ting, Wang, Jie-Yu, Pei, Jian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6022156/
https://www.ncbi.nlm.nih.gov/pubmed/30034713
http://dx.doi.org/10.1039/c6sc01380e