Diastereodivergent combined carbometalation/zinc homologation/C–C fragmentation reaction as an efficient tool to prepare acyclic allylic quaternary carbon stereocenters

A new strategy has been developed to construct enantiomerically enriched acyclic allylic quaternary carbon stereocenters in a single-pot operation through a combined carbometalation/zinc homologation/fragmentation sequence. Proper tuning of the reaction conditions enables the synthesis of the two en...

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Detalles Bibliográficos
Autores principales: Roy, Sudipta Raha, Didier, Dorian, Kleiner, Amir, Marek, Ilan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6022242/
https://www.ncbi.nlm.nih.gov/pubmed/30034740
http://dx.doi.org/10.1039/c6sc02191c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6022242/
https://www.ncbi.nlm.nih.gov/pubmed/30034740
http://dx.doi.org/10.1039/c6sc02191c

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