Preparation of an ion with the highest calculated proton affinity: ortho-diethynylbenzene dianion

Owing to the increased proton affinity that results from additional negative charges, multiply-charged anions have been proposed as one route to prepare and access a range of new and powerful “superbases”. Paradoxically, while the additional electrons in polyanions increase basicity they serve to di...

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Detalles Bibliográficos
Autores principales: Poad, Berwyck L. J., Reed, Nicholas D., Hansen, Christopher S., Trevitt, Adam J., Blanksby, Stephen J., Mackay, Emily G., Sherburn, Michael S., Chan, Bun, Radom, Leo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6024202/
https://www.ncbi.nlm.nih.gov/pubmed/30034765
http://dx.doi.org/10.1039/c6sc01726f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6024202/
https://www.ncbi.nlm.nih.gov/pubmed/30034765
http://dx.doi.org/10.1039/c6sc01726f

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