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Preparation of an ion with the highest calculated proton affinity: ortho-diethynylbenzene dianion
Owing to the increased proton affinity that results from additional negative charges, multiply-charged anions have been proposed as one route to prepare and access a range of new and powerful “superbases”. Paradoxically, while the additional electrons in polyanions increase basicity they serve to di...
| Autores principales: | , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6024202/ https://www.ncbi.nlm.nih.gov/pubmed/30034765 http://dx.doi.org/10.1039/c6sc01726f |