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Intramolecular multi-bond strain: the unrecognized side of the dichotomy of conjugated systems
Electron conjugation stabilizes unsaturated systems and diminishes the differences among bond distances. Experimentally, Kistiakowsky and coworkers first measured and noticed the difference between the hydrogenation heats of carbon–carbon double bonds in conjugated systems. For instance, the hydroge...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6024246/ https://www.ncbi.nlm.nih.gov/pubmed/30034728 http://dx.doi.org/10.1039/c6sc00454g |