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Rationalization of Asymmetric Amplification via Autocatalysis Triggered by Isotopically Chiral Molecules
[Image: see text] Asymmetric amplification induced in the Soai autocatalytic reaction by chiral initiators that are enantiomeric only by virtue of an isotope, e.g., −CH(3) vs CD(3)–, is examined by spectroscopic, kinetic, and DFT modeling studies to help understand requirements for the emergence of...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6026777/ https://www.ncbi.nlm.nih.gov/pubmed/29974074 http://dx.doi.org/10.1021/acscentsci.8b00297 |