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Stretching vibration is a spectator in nucleophilic substitution

How chemical reactions are influenced by reactant vibrational excitation is a long-standing question at the core of chemical reaction dynamics. In reactions of polyatomic molecules, where the Polanyi rules are not directly applicable, certain vibrational modes can act as spectators. In nucleophilic...

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Detalles Bibliográficos
Autores principales: Stei, Martin, Carrascosa, Eduardo, Dörfler, Alexander, Meyer, Jennifer, Olasz, Balázs, Czakó, Gábor, Li, Anyang, Guo, Hua, Wester, Roland
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Association for the Advancement of Science 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6035035/
https://www.ncbi.nlm.nih.gov/pubmed/29984305
http://dx.doi.org/10.1126/sciadv.aas9544