Cobalt-catalyzed C–H cyanations: Insights into the reaction mechanism and the role of London dispersion

Carboxylate-assisted cobalt(III)-catalyzed C–H cyanations are highly efficient processes for the synthesis of (hetero)aromatic nitriles. We have now analyzed the cyanation of differently substituted 2-phenylpyridines in detail computationally by density functional theory and also experimentally. Bas...

Descripción completa

Detalles Bibliográficos
Autores principales: Detmar, Eric, Müller, Valentin, Zell, Daniel, Ackermann, Lutz, Breugst, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2018
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6036974/
https://www.ncbi.nlm.nih.gov/pubmed/30013680
http://dx.doi.org/10.3762/bjoc.14.130

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6036974/
https://www.ncbi.nlm.nih.gov/pubmed/30013680
http://dx.doi.org/10.3762/bjoc.14.130

Ejemplares similares