Visible light-mediated difluoroalkylation of electron-deficient alkenes

A method for the reductive difluoroalkylation of electron-deficient alkenes using 1,1-difluorinated iodides mediated by irradiation with blue light is described. The reaction involves radical addition of 1,1-difluorinated radicals at the double bond followed by hydrogen atom transfer from sodium cya...

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Detalles Bibliográficos
Autores principales: Supranovich, Vyacheslav I, Levin, Vitalij V, Struchkova, Marina I, Hu, Jinbo, Dilman, Alexander D
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2018
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6036985/
https://www.ncbi.nlm.nih.gov/pubmed/30013689
http://dx.doi.org/10.3762/bjoc.14.139

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6036985/
https://www.ncbi.nlm.nih.gov/pubmed/30013689
http://dx.doi.org/10.3762/bjoc.14.139

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