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Visible light-mediated difluoroalkylation of electron-deficient alkenes
A method for the reductive difluoroalkylation of electron-deficient alkenes using 1,1-difluorinated iodides mediated by irradiation with blue light is described. The reaction involves radical addition of 1,1-difluorinated radicals at the double bond followed by hydrogen atom transfer from sodium cya...
Autores principales: | Supranovich, Vyacheslav I, Levin, Vitalij V, Struchkova, Marina I, Hu, Jinbo, Dilman, Alexander D |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6036985/ https://www.ncbi.nlm.nih.gov/pubmed/30013689 http://dx.doi.org/10.3762/bjoc.14.139 |
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