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Crystal structures of (aceto­nitrile-κN)tris­(pyridine-4-thio­amide-κN)bis­(thio­cyanate-κN)cobalt(II) aceto­nitrile disolvate and tetra­kis­(pyridine-4-thio­amide-κN)bis­(thio­cyanate-κN)nickel(II) methanol penta­solvate

Reaction of Co(NCS)(2) or Ni(NCS)(2) with pyridine-4-thio­amide in different solvents led to the formation of two compounds with composition [Co(NCS)(2)(C(2)H(3)N)(C(6)H(6)N(2)S)(3)]·2CH(3)CN (1) and [Ni(NCS)(2)(C(6)H(6)N(2)S)(4)]·5CH(3)OH (2), respectively. The asymmetric unit of compound 1 consist...

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Detalles Bibliográficos
Autores principales: Neumann, Tristan, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6038621/
https://www.ncbi.nlm.nih.gov/pubmed/30002895
http://dx.doi.org/10.1107/S2056989018007612