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Spontaneous enanti­omorphism in poly-phased alkaline salts of tris­(oxalato)ferrate(III): crystal structure of cubic NaRb(5)[Fe(C(2)O(4))(3)](2)

We show here that the phenomenon of spontaneous resolution of enanti­omers occurs during the crystallization of the sodium and rubidium double salts of the transition metal complex tris­(oxalato)ferrate(III), namely sodium penta­rubidium bis­[tris­(oxalato)ferrate(III)], NaRb(5)[Fe(C(2)O(4))(3)](2)....

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Detalles Bibliográficos
Autores principales: Piro, O. E., Echeverría, G. A., Baran, E. J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6038628/
https://www.ncbi.nlm.nih.gov/pubmed/30002883
http://dx.doi.org/10.1107/S2056989018008022