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Spontaneous enantiomorphism in poly-phased alkaline salts of tris(oxalato)ferrate(III): crystal structure of cubic NaRb(5)[Fe(C(2)O(4))(3)](2)
We show here that the phenomenon of spontaneous resolution of enantiomers occurs during the crystallization of the sodium and rubidium double salts of the transition metal complex tris(oxalato)ferrate(III), namely sodium pentarubidium bis[tris(oxalato)ferrate(III)], NaRb(5)[Fe(C(2)O(4))(3)](2)....
Autores principales: | Piro, O. E., Echeverría, G. A., Baran, E. J. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6038628/ https://www.ncbi.nlm.nih.gov/pubmed/30002883 http://dx.doi.org/10.1107/S2056989018008022 |
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