Crystal structure of (2,2′-bi­pyridine-κ(2) N,N′)-trans-bis­(tert-butyl­dimethyl­sil­yloxy)-cis-dioxidomolybdenum(VI)

In the title compound, [((t)BuSiMe(2)O)(2)MoO(2)(2,2′-bi­pyridine)] or [Mo(C(6)H(15)OSi)(2)O(2)(C(10)H(8)N(2))], the Mo(VI) atom has a distorted octa­hedral environment with the sil­oxy substituents occupying the trans positions. The complex contains a rare (R (3)SiO)(2) MO(2) (M = Mo, W) structural...

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Detalles Bibliográficos
Autores principales: Minyaev, Mikhail E., Vinogradov, Alexander A., Nifant’ev, Ilya E., Churakov, Andrei V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6038637/
https://www.ncbi.nlm.nih.gov/pubmed/30002896
http://dx.doi.org/10.1107/S2056989018008472

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6038637/
https://www.ncbi.nlm.nih.gov/pubmed/30002896
http://dx.doi.org/10.1107/S2056989018008472

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