Crystal structure of (2,2′-bi­pyridine-κ(2) N,N′)-trans-bis­(tert-butyl­dimethyl­sil­yloxy)-cis-dioxidomolybdenum(VI)

In the title compound, [((t)BuSiMe(2)O)(2)MoO(2)(2,2′-bi­pyridine)] or [Mo(C(6)H(15)OSi)(2)O(2)(C(10)H(8)N(2))], the Mo(VI) atom has a distorted octa­hedral environment with the sil­oxy substituents occupying the trans positions. The complex contains a rare (R (3)SiO)(2) MO(2) (M = Mo, W) structural...

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Autores principales: Minyaev, Mikhail E., Vinogradov, Alexander A., Nifant’ev, Ilya E., Churakov, Andrei V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6038637/
https://www.ncbi.nlm.nih.gov/pubmed/30002896
http://dx.doi.org/10.1107/S2056989018008472
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author Minyaev, Mikhail E.
Vinogradov, Alexander A.
Nifant’ev, Ilya E.
Churakov, Andrei V.
author_facet Minyaev, Mikhail E.
Vinogradov, Alexander A.
Nifant’ev, Ilya E.
Churakov, Andrei V.
author_sort Minyaev, Mikhail E.
collection PubMed
description In the title compound, [((t)BuSiMe(2)O)(2)MoO(2)(2,2′-bi­pyridine)] or [Mo(C(6)H(15)OSi)(2)O(2)(C(10)H(8)N(2))], the Mo(VI) atom has a distorted octa­hedral environment with the sil­oxy substituents occupying the trans positions. The complex contains a rare (R (3)SiO)(2) MO(2) (M = Mo, W) structural motif and was formed in a reaction between sodium molybdate and tert-butyl­dimethyl­silyl chloride in the presence of 2,2-bi­pyridine. In the crystal, neighbouring mol­ecules are linked by C—H⋯O=Mo hydrogen bonds, forming chains propagating along the a-axis direction.
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spelling pubmed-60386372018-07-12 Crystal structure of (2,2′-bi­pyridine-κ(2) N,N′)-trans-bis­(tert-butyl­dimethyl­sil­yloxy)-cis-dioxidomolybdenum(VI) Minyaev, Mikhail E. Vinogradov, Alexander A. Nifant’ev, Ilya E. Churakov, Andrei V. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, [((t)BuSiMe(2)O)(2)MoO(2)(2,2′-bi­pyridine)] or [Mo(C(6)H(15)OSi)(2)O(2)(C(10)H(8)N(2))], the Mo(VI) atom has a distorted octa­hedral environment with the sil­oxy substituents occupying the trans positions. The complex contains a rare (R (3)SiO)(2) MO(2) (M = Mo, W) structural motif and was formed in a reaction between sodium molybdate and tert-butyl­dimethyl­silyl chloride in the presence of 2,2-bi­pyridine. In the crystal, neighbouring mol­ecules are linked by C—H⋯O=Mo hydrogen bonds, forming chains propagating along the a-axis direction. International Union of Crystallography 2018-06-15 /pmc/articles/PMC6038637/ /pubmed/30002896 http://dx.doi.org/10.1107/S2056989018008472 Text en © Minyaev et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Minyaev, Mikhail E.
Vinogradov, Alexander A.
Nifant’ev, Ilya E.
Churakov, Andrei V.
Crystal structure of (2,2′-bi­pyridine-κ(2) N,N′)-trans-bis­(tert-butyl­dimethyl­sil­yloxy)-cis-dioxidomolybdenum(VI)
title Crystal structure of (2,2′-bi­pyridine-κ(2) N,N′)-trans-bis­(tert-butyl­dimethyl­sil­yloxy)-cis-dioxidomolybdenum(VI)
title_full Crystal structure of (2,2′-bi­pyridine-κ(2) N,N′)-trans-bis­(tert-butyl­dimethyl­sil­yloxy)-cis-dioxidomolybdenum(VI)
title_fullStr Crystal structure of (2,2′-bi­pyridine-κ(2) N,N′)-trans-bis­(tert-butyl­dimethyl­sil­yloxy)-cis-dioxidomolybdenum(VI)
title_full_unstemmed Crystal structure of (2,2′-bi­pyridine-κ(2) N,N′)-trans-bis­(tert-butyl­dimethyl­sil­yloxy)-cis-dioxidomolybdenum(VI)
title_short Crystal structure of (2,2′-bi­pyridine-κ(2) N,N′)-trans-bis­(tert-butyl­dimethyl­sil­yloxy)-cis-dioxidomolybdenum(VI)
title_sort crystal structure of (2,2′-bi­pyridine-κ(2) n,n′)-trans-bis­(tert-butyl­dimethyl­sil­yloxy)-cis-dioxidomolybdenum(vi)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6038637/
https://www.ncbi.nlm.nih.gov/pubmed/30002896
http://dx.doi.org/10.1107/S2056989018008472
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