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Crystal structure of (2,2′-bipyridine-κ(2) N,N′)-trans-bis(tert-butyldimethylsilyloxy)-cis-dioxidomolybdenum(VI)
In the title compound, [((t)BuSiMe(2)O)(2)MoO(2)(2,2′-bipyridine)] or [Mo(C(6)H(15)OSi)(2)O(2)(C(10)H(8)N(2))], the Mo(VI) atom has a distorted octahedral environment with the siloxy substituents occupying the trans positions. The complex contains a rare (R (3)SiO)(2) MO(2) (M = Mo, W) structural...
Autores principales: | Minyaev, Mikhail E., Vinogradov, Alexander A., Nifant’ev, Ilya E., Churakov, Andrei V. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6038637/ https://www.ncbi.nlm.nih.gov/pubmed/30002896 http://dx.doi.org/10.1107/S2056989018008472 |
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