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Protonated nucleobases are not fully ionized in their chloride salt crystals and form metastable base pairs further stabilized by the surrounding anions

This paper presents experimental charge-density studies of cytosinium chloride, adeninium chloride hemihydrate and guaninium dichloride crystals based on ultra-high-resolution X-ray diffraction data and extensive theoretical calculations. The results confirm that the cohesive energies of the studied...

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Detalles Bibliográficos
Autores principales: Kumar, Prashant, Cabaj, Malgorzata Katarzyna, Pazio, Aleksandra, Dominiak, Paulina Maria
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6038959/
https://www.ncbi.nlm.nih.gov/pubmed/30002846
http://dx.doi.org/10.1107/S2052252518006346