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Symmetry breaking by enzyme-catalyzed epoxide hydrolysis
Janfalk Carlsson et al. [IUCrJ (2018), 5, 269–282] describe studies on factors determining selective ring opening of methylstyrene oxide stereoisomers by the epoxide hydrolase StEH1. The stereo-differentiating step is selective hydrolysis of an alkylated intermediate formed by reaction of the epoxid...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6038963/ https://www.ncbi.nlm.nih.gov/pubmed/30002837 http://dx.doi.org/10.1107/S2052252518007005 |