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Roles of Hydrogen Bonding in Proton Transfer to κ(P),κ(N),κ(P)-N(CH(2)CH(2)P(i)Pr(2))(2)-Ligated Nickel Pincer Complexes

[Image: see text] The nickel PNP pincer complex (((i)Pr)PNP)NiPh (((i)Pr)PNP = κ(P),κ(N),κ(P)-N(CH(2)CH(2)P(i)Pr(2))(2)) was prepared by reacting (((i)Pr)PNP)NiBr with PhMgCl or deprotonating [(((i)Pr)PN(H)P)NiPh]Y (((i)Pr)PN(H)P = κ(P),κ(N),κ(P)-HN(CH(2)CH(2)P(i)Pr(2))(2); Y = Br, PF(6)) with KO(t)...

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Detalles Bibliográficos
Autores principales: Wellala, Nadeesha P. N., Luebking, John D., Krause, Jeanette A., Guan, Hairong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6045406/
https://www.ncbi.nlm.nih.gov/pubmed/30023906
http://dx.doi.org/10.1021/acsomega.8b00777