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Roles of Hydrogen Bonding in Proton Transfer to κ(P),κ(N),κ(P)-N(CH(2)CH(2)P(i)Pr(2))(2)-Ligated Nickel Pincer Complexes
[Image: see text] The nickel PNP pincer complex (((i)Pr)PNP)NiPh (((i)Pr)PNP = κ(P),κ(N),κ(P)-N(CH(2)CH(2)P(i)Pr(2))(2)) was prepared by reacting (((i)Pr)PNP)NiBr with PhMgCl or deprotonating [(((i)Pr)PN(H)P)NiPh]Y (((i)Pr)PN(H)P = κ(P),κ(N),κ(P)-HN(CH(2)CH(2)P(i)Pr(2))(2); Y = Br, PF(6)) with KO(t)...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2018
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6045406/ https://www.ncbi.nlm.nih.gov/pubmed/30023906 http://dx.doi.org/10.1021/acsomega.8b00777 |