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Probing disorder in pyrochlore oxides using in situ synchrotron diffraction from levitated solids–A thermodynamic perspective

Pyrochlore, an ordered derivative of the defect fluorite structure, shows complex disordering behavior as a function of composition, temperature, pressure, and radiation damage. We propose a thermodynamic model to calculate the disordering enthalpies for several RE(2)Zr(2)O(7) (RE = Sm, Eu, Gd) pyro...

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Detalles Bibliográficos
Autores principales: Maram, Pardha S., Ushakov, Sergey V., Weber, Richard J. K., Benmore, Chris J., Navrotsky, Alexandra
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6045670/
https://www.ncbi.nlm.nih.gov/pubmed/30006557
http://dx.doi.org/10.1038/s41598-018-28877-x