Unlocking Structural Diversity in Gold(III) Hydrides: Unexpected Interplay of cis/trans-Influence on Stability, Insertion Chemistry, and NMR Chemical Shifts

[Image: see text] The synthesis of new families of stable or at least spectroscopically observable gold(III) hydride complexes is reported, including anionic cis-hydrido chloride, hydrido aryl, and cis-dihydride complexes. Reactions between (C^C)AuCl(PR(3)) and LiHBEt(3) afford the first examples of...

Descripción completa

Detalles Bibliográficos
Autores principales: Rocchigiani, Luca, Fernandez-Cestau, Julio, Chambrier, Isabelle, Hrobárik, Peter, Bochmann, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6047844/
https://www.ncbi.nlm.nih.gov/pubmed/29860842
http://dx.doi.org/10.1021/jacs.8b04478

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6047844/
https://www.ncbi.nlm.nih.gov/pubmed/29860842
http://dx.doi.org/10.1021/jacs.8b04478

Ejemplares similares