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Unlocking Structural Diversity in Gold(III) Hydrides: Unexpected Interplay of cis/trans-Influence on Stability, Insertion Chemistry, and NMR Chemical Shifts

[Image: see text] The synthesis of new families of stable or at least spectroscopically observable gold(III) hydride complexes is reported, including anionic cis-hydrido chloride, hydrido aryl, and cis-dihydride complexes. Reactions between (C^C)AuCl(PR(3)) and LiHBEt(3) afford the first examples of...

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Detalles Bibliográficos
Autores principales:	Rocchigiani, Luca, Fernandez-Cestau, Julio, Chambrier, Isabelle, Hrobárik, Peter, Bochmann, Manfred
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2018
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6047844/ https://www.ncbi.nlm.nih.gov/pubmed/29860842 http://dx.doi.org/10.1021/jacs.8b04478

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