The 3(rd) degree of biomimetism: associating the cavity effect, Zn(II) coordination and internal base assistance for guest binding and activation

The synthesis and characterization of a resorcinarene-based tetra(imidazole) ligand is reported. The properties of the corresponding Zn(II) complex are studied in depth, notably by NMR spectroscopy. In MeCN, acid–base titration reveals that one out of the four imidazole arms is hemi-labile and can b...

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Detalles Bibliográficos
Autores principales: Parrot, A., Collin, S., Bruylants, G., Reinaud, O.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6048688/
https://www.ncbi.nlm.nih.gov/pubmed/30079177
http://dx.doi.org/10.1039/c8sc01129j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6048688/
https://www.ncbi.nlm.nih.gov/pubmed/30079177
http://dx.doi.org/10.1039/c8sc01129j

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