Cargando…

The intramolecular hydrogen bonded–halogen bond: a new strategy for preorganization and enhanced binding

Natural and synthetic molecules use weak noncovalent forces to preorganize structure and enable remarkable function. Herein, we introduce the intramolecular hydrogen bonded–halogen bond (HB–XB) as a novel method to preorganize halogen bonding (XBing) molecules, while generating a polarization-enhanc...

Descripción completa

Detalles Bibliográficos
Autores principales: Riel, Asia Marie S., Decato, Daniel A., Sun, Jiyu, Massena, Casey J., Jessop, Morly J., Berryman, Orion B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6050591/
https://www.ncbi.nlm.nih.gov/pubmed/30079195
http://dx.doi.org/10.1039/c8sc01973h