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Formal Giese addition of C(sp(3))–H nucleophiles enabled by visible light mediated Ni catalysis of triplet enone diradicals
An unprecedented utilization of triplet excited enones in Ni-catalysis enabled a formal Giese addition of C(sp(3))–H nucleophiles. This mechanism-based approach has greatly widened the reaction scope, allowing the synthesis of previously inaccessible structures. In this process, the enone diradical...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Royal Society of Chemistry
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6050596/ https://www.ncbi.nlm.nih.gov/pubmed/30079192 http://dx.doi.org/10.1039/c8sc01827h |