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Visible light-promoted ring-opening functionalization of unstrained cycloalkanols via inert C–C bond scission

Described herein is a novel, useful, visible light-promoted ring-opening functionalization of unstrained cycloalkanols. Upon scission of an inert cyclic C–C σ-bond, a set of medium- and large-sized rings are readily brominated under mild reaction conditions to afford the corresponding distal bromo-s...

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Detalles Bibliográficos
Autores principales: Wang, Dongping, Mao, Jincheng, Zhu, Chen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6050598/
https://www.ncbi.nlm.nih.gov/pubmed/30079191
http://dx.doi.org/10.1039/c8sc01763h