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Molecular dynamic staircases: all-carbon axial chiral “Geländer” structures

Herein, the syntheses of two tightly packed all-carbon “Geländer” molecules with axial chirality are described. Motivated by our previous results, we further reduced the bridge length by excluding the heteroatoms. The absolute configuration was determined by comparison of the measured and calculated...

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Detalles Bibliográficos
Autores principales: Mannancherry, Rajesh, Rickhaus, Michel, Häussinger, Daniel, Prescimone, Alessandro, Mayor, Marcel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6050599/
https://www.ncbi.nlm.nih.gov/pubmed/30079185
http://dx.doi.org/10.1039/c8sc01707g