Mechanistic insights into the S(N)2-type reactivity of aryl-Co(iii) masked-carbenes for C–C bond forming transformations

Herein we describe the synthesis and characterization of a family of C-metalated aryl-Co(iii) enolates, which can be considered as masked-carbenes, using diazoacetates as coupling partners. These species have been proved to be necessary intermediates in the C(sp(2))–C(sp(3)) bond forming event to ob...

Descripción completa

Detalles Bibliográficos
Autores principales: Planas, O., Roldán-Gómez, S., Martin-Diaconescu, V., Luis, J. M., Company, A., Ribas, X.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6050605/
https://www.ncbi.nlm.nih.gov/pubmed/30079183
http://dx.doi.org/10.1039/c8sc00851e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6050605/
https://www.ncbi.nlm.nih.gov/pubmed/30079183
http://dx.doi.org/10.1039/c8sc00851e

Ejemplares similares