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Mechanistic insights into the S(N)2-type reactivity of aryl-Co(iii) masked-carbenes for C–C bond forming transformations
Herein we describe the synthesis and characterization of a family of C-metalated aryl-Co(iii) enolates, which can be considered as masked-carbenes, using diazoacetates as coupling partners. These species have been proved to be necessary intermediates in the C(sp(2))–C(sp(3)) bond forming event to ob...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6050605/ https://www.ncbi.nlm.nih.gov/pubmed/30079183 http://dx.doi.org/10.1039/c8sc00851e |