Cargando…

(Salen)Mn(iii)-catalyzed chemoselective acylazidation of olefins

We describe a (salen)Mn(iii)-catalyzed three-component reaction of aldehydes, olefins, and sodium azide for the installation of two useful groups (C[double bond, length as m-dash]O and N(3)) into the double bond. Traditionally, (salen)Mn(iii) in conjunction with iodosobenzene is a classical catalysi...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhang, Liang, Liu, Shuya, Zhao, Zhiguo, Su, Hongmei, Hao, Jingcheng, Wang, Yao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6053955/
https://www.ncbi.nlm.nih.gov/pubmed/30090296
http://dx.doi.org/10.1039/c8sc01882k