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Origin of stereoselectivity in the amination of alcohols using cooperative asymmetric dual catalysis involving chiral counter-ions

Asymmetric catalysis using two chiral catalysts in combination using one-pot reaction conditions is in its initial stages of development and understanding. We employ density functional theory (SMD((toluene))/M06/6-31G**,SDD(Ir)) computations to shed light on the action of chiral phosphoric acid and...

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Detalles Bibliográficos
Autores principales: Tribedi, Soumi, Hadad, Christopher M., Sunoj, Raghavan B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6053974/
https://www.ncbi.nlm.nih.gov/pubmed/30090300
http://dx.doi.org/10.1039/c8sc01433g