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Origin of stereoselectivity in the amination of alcohols using cooperative asymmetric dual catalysis involving chiral counter-ions
Asymmetric catalysis using two chiral catalysts in combination using one-pot reaction conditions is in its initial stages of development and understanding. We employ density functional theory (SMD((toluene))/M06/6-31G**,SDD(Ir)) computations to shed light on the action of chiral phosphoric acid and...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6053974/ https://www.ncbi.nlm.nih.gov/pubmed/30090300 http://dx.doi.org/10.1039/c8sc01433g |