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The functional role of the structure of the dioxo-isobacteriochlorin in the catalytic site of cytochrome cd(1) for the reduction of nitrite

Cytochrome cd(1) is a key enzyme in bacterial denitrification and catalyzes one-electron reduction of nitrite (NO(2)(–)) to nitric oxide (NO) at the heme d(1) center under anaerobic conditions. The heme d(1) has a unique dioxo-isobacteriochlorin structure and is present only in cytochrome cd(1). To...

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Detalles Bibliográficos
Autores principales: Fujii, Hiroshi, Yamaki, Daisuke, Ogura, Takashi, Hada, Masahiko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6054029/
https://www.ncbi.nlm.nih.gov/pubmed/30090283
http://dx.doi.org/10.1039/c5sc04825g