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The multiple bonding in heavier group 14 element alkene analogues is stabilized mainly by dispersion force effects

The structures and bonding in the heavier group 14 element olefin analogues [E{CH(SiMe(3))(2)}(2)](2) and [E{N(SiMe(3))(2)}(2)](2) (E = Ge, Sn, or Pb) and their dissociation into :E{CH(SiMe(3))(2)}(2) and :E{N(SiMe(3))(2)}(2) monomers were studied computationally using hybrid density functional theo...

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Detalles Bibliográficos
Autores principales: Guo, Jing-Dong, Liptrot, David J., Nagase, Shigeru, Power, Philip P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6054042/
https://www.ncbi.nlm.nih.gov/pubmed/30090241
http://dx.doi.org/10.1039/c5sc02707a