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The multiple bonding in heavier group 14 element alkene analogues is stabilized mainly by dispersion force effects
The structures and bonding in the heavier group 14 element olefin analogues [E{CH(SiMe(3))(2)}(2)](2) and [E{N(SiMe(3))(2)}(2)](2) (E = Ge, Sn, or Pb) and their dissociation into :E{CH(SiMe(3))(2)}(2) and :E{N(SiMe(3))(2)}(2) monomers were studied computationally using hybrid density functional theo...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6054042/ https://www.ncbi.nlm.nih.gov/pubmed/30090241 http://dx.doi.org/10.1039/c5sc02707a |