Silicon(i) chemistry: the NHC-stabilised silicon(i) halides Si(2)X(2)(Idipp)(2) (X = Br, I) and the disilicon(i)-iodido cation [Si(2)(I)(Idipp)(2)](+)

An efficient method for the synthesis of the NHC-stabilised Si(i) halides Si(2)X(2)(Idipp)(2) (2-X, X = Cl, Br, I; Idipp = C[N(C(6)H(3)-2,6-iPr(2))CH](2)) was developed, which involves the oxidation of Si(2)(Idipp)(2) (1) with 1,2-dihaloethanes. Halogenation of 1 is a diastereoselective reaction lea...

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Detalles Bibliográficos
Autores principales: Arz, Marius I., Geiß, Daniel, Straßmann, Martin, Schnakenburg, Gregor, Filippou, Alexander C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6054044/
https://www.ncbi.nlm.nih.gov/pubmed/30090270
http://dx.doi.org/10.1039/c5sc02681d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6054044/
https://www.ncbi.nlm.nih.gov/pubmed/30090270
http://dx.doi.org/10.1039/c5sc02681d

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