Cargando…
Silicon(i) chemistry: the NHC-stabilised silicon(i) halides Si(2)X(2)(Idipp)(2) (X = Br, I) and the disilicon(i)-iodido cation [Si(2)(I)(Idipp)(2)](+)
An efficient method for the synthesis of the NHC-stabilised Si(i) halides Si(2)X(2)(Idipp)(2) (2-X, X = Cl, Br, I; Idipp = C[N(C(6)H(3)-2,6-iPr(2))CH](2)) was developed, which involves the oxidation of Si(2)(Idipp)(2) (1) with 1,2-dihaloethanes. Halogenation of 1 is a diastereoselective reaction lea...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6054044/ https://www.ncbi.nlm.nih.gov/pubmed/30090270 http://dx.doi.org/10.1039/c5sc02681d |