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Selective acceleration of disfavored enolate addition reactions by anion–π interactions

In chemistry and biology, cation–π interactions contribute significantly to many important transformations. In sharp contrast, reactions accomplished with support from the complementary anion–π interactions are essentially unknown. In this report, we show that anion–π interactions can determine the...

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Detalles Bibliográficos
Autores principales: Zhao, Yingjie, Benz, Sebastian, Sakai, Naomi, Matile, Stefan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6054047/
https://www.ncbi.nlm.nih.gov/pubmed/30090238
http://dx.doi.org/10.1039/c5sc02563j