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Non-classical selectivities in the reduction of alkenes by cobalt-mediated hydrogen atom transfer

Classical methods for alkene hydrogenation typically reduce less-substituted or more-strained alkenes, or those in proximity to a directing group, most rapidly. Here we describe a cobalt-mediated hydrogenation protocol that provides complementary selectivities in the reduction of several classes of...

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Detalles Bibliográficos
Autores principales: Ma, Xiaoshen, Herzon, Seth B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6054054/
https://www.ncbi.nlm.nih.gov/pubmed/30090243
http://dx.doi.org/10.1039/c5sc02476e