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Non-classical selectivities in the reduction of alkenes by cobalt-mediated hydrogen atom transfer
Classical methods for alkene hydrogenation typically reduce less-substituted or more-strained alkenes, or those in proximity to a directing group, most rapidly. Here we describe a cobalt-mediated hydrogenation protocol that provides complementary selectivities in the reduction of several classes of...
Autores principales: | Ma, Xiaoshen, Herzon, Seth B. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6054054/ https://www.ncbi.nlm.nih.gov/pubmed/30090243 http://dx.doi.org/10.1039/c5sc02476e |
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